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Updated: Sep 16, 2025

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[2,3]-Sigmatropic重新排列与[1.1.1]螺旋进行了重新排列

Suparnak Midya1, Aksar Ali1, Durga Prasad Hari2

  • 1Department of Organic Chemistry, Indian Institute of Science, Bangalore, India.

Nature communications
|July 7, 2025
PubMed
概括

[1.1.1]作为一种新型[2,3]-sigmatropic重组的碳素前体,有效地形成基或基甲基环. 这种方法还可以合成有价值的二[2.1.1]hexanes,宝贵的二异构体.

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