液相溶液的波动理论:剪切粘度
Yury A Budkov1,2,3, Nikolai N Kalikin1,4, Petr E Brandyshev1,2
1Laboratory of Computational Physics, HSE University, Tallinskaya st. 34, 123458 Moscow, Russia.
The Journal of chemical physics
|July 8, 2025
概括
本研究提出了一种新的理论,用于描述非平衡液体混合物,并计算诸如剪切粘度之类的运输特性. 该方法扩展了现有的方法,以准确地建模复杂的液体系统.
科学领域:
- 物理化学 物理化学
- 化学物理 化学物理
- 统计力学 统计力学
背景情况:
- 描述超出平衡状态的液体和混合物,特别是它们的运输特性,是一个重大挑战.
- 现有的理论往往难以准确地建模不平衡的液相系统.
研究的目的:
- 为多元组件液相溶液引入一种新的现象学不平衡理论.
- 为了在这些系统中计算运输特性,特别是剪切粘度.
主要方法:
- 开发了一个基于不平衡统计力学的领域理论框架.
- 纳入了准静止的度波动,与经典密度函数理论保持一致.
- 扩展了Dean-Kawasaki随机密度函数理论用于剪切粘度计算.
主要成果:
- 在单溶液溶液中获得剪切粘度的一般公式.
- 成功地复制了各种系统的既定结果,包括软核粒子和硬球.
- 对近临界溶液和单元等离子体的行为获得了新的见解.
结论:
- 提出的现象学理论为非平衡液体混合物提供了有效的框架.
- 该方法精确计算了剪切粘度,验证了其对现有理论的扩展.
- 这种方法有助于更好地理解复杂液体系统中的运输特性.
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