接口偏好吸附和分子运动限制使3.2V高压超级电容器成为可能
Yiheng Qi1, Xuanchi Li1, Chuang Bao1
1State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou, 310027, Zhejiang Province, China.
ChemPlusChem
|July 8, 2025
概括
将乙烯碳酸盐 (EC) 添加到基于乙二 (AN) 的电解质中,可以通过防止副作用来提高超级电容器的性能. 这种AN-EC电解质可以实现更宽的电压窗口和更好的稳定性,用于先进的能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 由于电压窗口狭窄,商用超级电容器的储能有限.
- 在电极接口的电解质分解,特别是酸 (AN),导致性能降低.
研究的目的:
- 为了提高超级电容器的基于AN的电解质的电化学稳定性.
- 为了抑制副作用,改善电压窗口和循环性能.
主要方法:
- 将乙烯碳酸盐 (EC) 引入基于AN的电解质中.
- 理论计算和实验表征 (例如,电化学测试).
- 对EC吸附和AN扩散抑制机制的分析.
主要成果:
- 该AN-EC电解质实现了3.2V的电压窗口.
- 经证实增强的循环稳定性,在3万个循环后保持70%的容量.
- 实现了优越的能量和功率密度 (33.3 Wh kg-1 在 749 W kg-1 和 17.6 Wh kg-1 在 9,883 W kg-1).
结论:
- 通过优先吸附和减少扩散,EC添加有效抑制AN的界面分解.
- 开发的AN-EC电解质为高性能超级电容器提供了一个有前途的战略.
- 为设计用于先进的电化学能量存储的稳定电解质提供了一个框架.
更多相关视频
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
4.6K
07:45Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
10.1K
相关概念视频
MOS Capacitor
988
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
988
Dielectric Polarization in a Capacitor
5.0K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
5.0K
Energy Stored in Capacitors
636
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
636
Capacitors
542
Capacitors play a crucial role in car radios, where they filter and store frequencies to ensure clear signal reception. Essentially serving as energy storage devices, capacitors store energy within their electric field and are composed of two parallel conducting plates separated by a dielectric.
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
542
Capacitor With A Dielectric
4.2K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.2K
Energy Stored in a Capacitor
3.8K
When an archer pulls the string in a bow, he saves the work done in the form of elastic potential energy. When he releases the string, the potential energy is released as kinetic energy of the arrow. A capacitor works on the same principle in which the work done is saved as electric potential energy. The potential energy (UC) could be calculated by measuring the work done (W) to charge the capacitor.
3.8K
