在大气中突如其来的甘油酸硫酸的气相形成
Haowei Sun1,2, Yuliang Liu1,2, Wei Nie1,2
1Joint International Research Laboratory of Atmospheric and Earth System Research, School of Atmospheric Sciences, Nanjing University, Nanjing 210023, China.
Environmental science & technology
|July 8, 2025
概括
气相有机硫酸盐 (OSs),如甘油酸硫酸盐 (GAS),在城市空气中被检测到,挑战了传统的观点. 这一发现为低挥发性有机化合物提供了新的大气化学途径.
科学领域:
- 大气化学 大气化学
- 环境科学 环境科学
- 气溶科学 气溶科学
背景情况:
- 有机硫酸盐 (OSs) 是二次有机气溶的关键标记物,传统上存在于颗粒物中.
- 气相存在和OS的来源在很大程度上未被检测到,并且不太了解.
研究的目的:
- 为城市大气中持续存在的气相有机硫酸盐提供观察证据.
- 研究气相有机硫酸盐的形成路径和分离行为.
主要方法:
- 利用先进的质谱技术进行检测和量化.
- 采用热吸附分析来确定挥发性.
- 与潜在的前体气体相关的气相OS度.
主要成果:
- 证实了气相甘油酸硫酸盐 (GAS) 在城市大气中持续存在.
- 观察到GAS明显的季节性和日间模式,在夏季中午达到顶峰,这表明光化学影响.
- 气体表现出极低的波动性,显著的气相分数超过了平衡预测,表明直接的气相来源.
- 提出了一种涉及SO3基和甘油酸 (GA) 的形成机制,具有高反应速率常数.
结论:
- 这项研究从根本上重塑了对OS源的理解,揭示了气相的重大贡献.
- 突出SO3在大气中形成低挥发性有机化合物的潜在作用.
- 这表明气相化学是大气有机硫酸盐的关键,以前被低估的来源.
相关概念视频
Acid Halides to Esters: Alcoholysis
3.1K
Alcoholysis is a nucleophilic acyl substitution reaction in which an alcohol functions as a nucleophile. Acid halides react with alcohol to produce esters. The mechanism proceeds in three steps:
3.1K
The Sulfur Cycle
46.4K
Sulfur, an important element in the chemical makeup of proteins, is recycled through the atmosphere and aquatic and terrestrial environments. Found in the atmosphere as sulfur dioxide (SO2), sulfur is released by decaying organisms, weathered rocks, geothermal vents, volcanos, and burning fossil fuels. It is deposited into the ecosystem, cycled through the biotic community, and either released back into the atmosphere as gas or deposited in marine sediment for long-term storage and eventual...
46.4K
Preparation and Reactions of Sulfides
5.1K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.1K
Aldehydes and Ketones with Alcohols: Hemiacetal Formation
7.1K
Similar to water, alcohols can add to the carbonyl carbon of the aldehydes and ketones. The addition of one molecule of alcohol to the carbonyl compound forms the hemiacetal or half acetal. As depicted below, in a hemiacetal, the carbon is directly linked to an OH and OR group.
7.1K
Acid Halides to Carboxylic Acids: Hydrolysis
2.9K
Hydrolysis of acid halides is a nucleophilic acyl substitution reaction in which acid halides react with water to give carboxylic acids. The reaction occurs readily and does not require acid or a base catalyst.
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic...
As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic...
2.9K
Fates of Pyruvate
9.0K
Pyruvate is the end product of glycolysis, where glucose is oxidized to pyruvate, simultaneously reducing NAD+ to NADH. Two molecules of ATP are also produced by substrate-level phosphorylation.
In aerobic organisms, pyruvate is metabolized via the citric acid cycle to produce reduced coenzymes NADH and FADH2. These coenzymes are then oxidized in the electron transport chain to produce ATP and, in the process, regenerate the NAD+ and FAD. As seen in some cell types and organisms, fermentation...
In aerobic organisms, pyruvate is metabolized via the citric acid cycle to produce reduced coenzymes NADH and FADH2. These coenzymes are then oxidized in the electron transport chain to produce ATP and, in the process, regenerate the NAD+ and FAD. As seen in some cell types and organisms, fermentation...
9.0K


