功能性电解质添加剂:一点盐/溶剂到高能量密度离子和金属电池的电解质
Chenrayan Senthil1, Amutha Subramani2, Ram K Gupta1,3
1National Institute for Materials Advancement, Pittsburg State University, Pittsburg, KS, 66762, USA.
Small (Weinheim an der Bergstrasse, Germany)
|July 9, 2025
概括
功能性电解质添加剂通过控制副作用和改善接口特性来提高离子/金属电池的性能和安全性. 本综述详细介绍了它们对电池寿命和运行稳定的影响.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 电解质对于离子/金属电池的性能至关重要,但会产生副作用,限制效率和安全性.
- 功能添加剂提供了一种有针对性的方法,通过修改电极-电解质接口来减轻这些问题.
研究的目的:
- 审查功能性电解质添加剂对提高离子/金属电池电化学性能,循环寿命和安全性的重大影响.
- 将添加剂分类并详细说明它们在解决特定电池挑战方面的机制作用.
主要方法:
- 综合性文献综述,重点关注离子/金属电池中的功能电解质添加剂.
- 根据其针对目标的行动和机制对添加剂进行分类.
主要成果:
- 添加剂有效地改善膜的形成,容量保留和稳定性在各种操作条件 (高压,宽温度) 中.
- 特定的添加剂减轻了诸如过充/放电,气体演变,易燃性和腐蚀等问题.
结论:
- 合理的电解质和添加剂工程是优化电池性能,循环寿命和安全的关键.
- 功能添加剂是克服当前基于电池技术的关键局限性的有希望的策略.
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