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在离子电池循环的阴极材料中扩散的含义:关于LiNi0.33Mn0.33Co0.33O2薄膜的案例研究

Erwin Hüger1,2, Harald Schmidt1,2

  • 1Clausthal University of Technology, Institute of Metallurgy, Solid State Kinetics Group, 38678 Clausthal-Zellerfeld, Germany.

The Journal of chemical physics
|July 9, 2025
PubMed
概括

可充电离子电池的LiNi0.33Mn0.33Co0.33O2薄膜阴极中的扩散动力学控制能力. 缓慢扩散将全容量限制在0.01C以下的非常低的循环速率上.

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The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
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