了解DINCH塑化PVC的溶解动力学:实验设计和应用建模
Ruben Denolf1, Jordy C Doolaege1, Elina Selmurzaeva1
1Laboratory for Circular Process Engineering (LCPE), Department of Green Chemistry and Technology, Ghent University Campus Kortrijk, Sint-Martens-Latemlaan 2B, 8500, Kortrijk, Belgium.
ChemSusChem
|July 9, 2025
概括
本研究分析了各种溶剂中的塑化聚乙烯 (P-PVC) 溶解动力学. 降低颗粒大小和增加温度加速P-PVC回收,NMP是最有效的溶剂.
科学领域:
- 聚合物科学 聚合物科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 聚合物溶解-沉回收对于提高塑料回收率至关重要.
- 了解溶解动力学对于优化塑料废物回收过程至关重要.
研究的目的:
- 分析塑化聚乙烯 (P-PVC) 在不同溶剂中的溶解动力学.
- 为了研究颗粒大小和温度对P-PVC溶解的影响.
- 为了模拟P-PVC的溶解行为.
主要方法:
- 在P-PVC中进行的溶解动力学实验包括N-甲基-2-pyrrolidinone (NMP),cyclohexanone,methyl ethyl ketone (MEK) 和2-methyltetrahydrofuran (2-MeTHF).
- 颗粒大小 (1090-2990微米) 和温度 (30-60°C) 都有所不同.
- 实验数据使用连锁解模型和基于第一阶扩散的模型进行了调整.
主要成果:
- 减少颗粒大小和增加温度减少了溶解时间.
- 聚合物和塑化剂 (DINCH) 的溶解同时发生.
- 溶解速率按照以下顺序进行:NMP > 环松 > MEK > 2-MeTHF.
结论:
- 在那些被测试的人中,NMP是P-PVC溶解最有效的溶剂.
- 运动模型的选择取决于溶剂的特性.
- 优化溶解条件可以提高塑料回收效率.
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