离子电池的Zwitterionic电解质添加剂:氨基基硫酸盐:氨基基硫酸盐
Ruize Sun1, Jingyu Yang1, Yongjin Fang1
1Hubei Key Laboratory of Electrochemical Power Sources, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, China.
一种新的zwitterionic添加剂,3- ((三乙) -1-硫酸盐 (TEAPS),通过在阳极和阴极表面形成保护接口来提高离子电池的性能. 这种多功能添加剂提高了烯碳酸盐电解质的循环稳定性.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 电池技术 电池技术
背景情况:
- 电解质添加剂对于离子电池 (LIB) 的性能至关重要.
- 目前的薄膜形成添加剂仅限于阳极或阴极,增加复杂性并降低效率.
研究的目的:
- 设计和合成一种用于LIBs的新型zwitterionic添加剂.
- 调查添加剂在阳极和阴极上形成稳定的接口的能力.
- 评估添加剂对电池循环性能的影响.
主要方法:
- 复合的zwitterionic 3-(三乙烯) --1-硫酸盐 (TEAPS). 这是一个非常好的方法.
- 在碳酸 (PC) 电解质中对石墨阳极和LiCoO2阴极表面进行吸附研究.
- 用TEAPS添加剂对LIBs的电化学循环性能评估.
主要成果:
- 在石墨阳极和LiCoO2阴极上,TEAPS有效地吸附.
- TEAPS有助于形成一个强大的F/S/N物种接口.
- 观察到,LIBs的循环表现显著改善.
结论:
- 齐维特的TEAPS添加剂通过在两个电极上运行来证明了它的多功能性.
- TEAPS促进了稳定和强大的接口层,增强了电池循环.
- 在开发高性能LIB方面,TEAPS是一个有希望的候选人.
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