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Updated: Sep 16, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

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替代模式对 thiopyridone异构体内部转换和系统间交叉的动态的影响

Douglas Garratt1, Sambit K Das2, Kacie J Nelson3

  • 1Linac Coherent Light Source (LCLS), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA.

Physical chemistry chemical physics : PCCP
|July 11, 2025
PubMed
概括

调查皮里 (TP) 异构体发现,替代模式显著影响超快的内部转换和系统间交叉动态. 由于中间稳定,正位异构体表现出比帕异构体更快的系统间交叉.

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Depending upon the different spatial orientation of the substituents, the disubstituted cycloalkanes exhibit two types of stereoisomers. The cis isomers have the substituents on the same side of the ring, whereas the trans isomers have the substituents on the opposite sides. These stereoisomers exhibit different physical properties and cannot be interconverted without breaking the carbon-carbon bonds.
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