进一步了解污水污泥在热化学处理过程中的转化
Satya Brat Tiwari1, Wei Ping Chan2, Andrei Veksha2
1Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, 637141, Singapore; School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore; Interdisciplinary Graduate Program, Nanyang Technological University, Singapore.
Journal of environmental management
|July 11, 2025
概括
本综述详细介绍了污水污泥 (SS) 热化学处理过程中的 (P) 转化. 了解P的行为是优化P恢复和关闭P周期的关键.
科学领域:
- 环境化学环境化学
- 废物管理 废物管理
- 材料科学 材料科学 材料科学
背景情况:
- 城市废水处理过程中的 (P) 转化影响其在污水污泥 (SS) 中的物种化.
- 精确地描述SS中P物种的特征对于有效的管理和恢复至关重要.
- 新兴的分析工具用于SS中的P表征仍然未得到充分利用.
研究的目的:
- 审查在污水污泥 (SS) 的热化学处理过程中 (P) 的命运.
- 分析工艺参数和原料特性对P转化的影响.
- 为优化SS的P恢复策略提供见解.
主要方法:
- 对现有的关于在焚烧,热解,热水处理和SS.的气化过程中的P转化文献的全面分析.
- 评估操作参数 (温度,保留时间,大气等) 的影响. 和原料特性 (组成,添加剂,颗粒大小,pH值).
- 对SS及其处理后的残留物中P特性分析方法的评估.
主要成果:
- 操作温度和SS化学成分是决定P命运的关键因素.
- 有机和酸盐在较低的温度下分解,在600°C以上转化为酸盐.
- 挥发通常发生在1100°C以上,但可以发生在1000°C以下的高有机SS.
结论:
- 了解P转化机制对于优化从SS灰/煤炭中P回收至关重要.
- 热化学处理条件显著影响P分化和恢复潜力.
- 这些知识有助于通过可持续的SS管理来关闭人为循环.
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