循环极化热激活延迟光小分子的状扰动策略:有机发光二极管应用的进展

Tianwen Fan1, Linxian Xu2, Hao Tang3

  • 1State Key Laboratory of Luminescent Materials and Devices, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.

概括

循环极化发光 (CPL) 分子可以通过实现100%的光利用来提高有机发光二极管 (OLED) 的效率. 本综述探讨了先进显示和成像技术中CPL材料的奇拉性扰动策略.

相关概念视频

Thermal Electrocyclic Reactions: Stereochemistry01:17

Thermal Electrocyclic Reactions: Stereochemistry

The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
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