在试点规模的砂造中,评估来自多重粘合剂系统的有害排放
Erika Garitaonandia1, Andoni Ibarra1, Angelika Kmita2
1AZTERLAN, Basque Research and Technology Alliance (BRTA), Aliendalde Auzunea, n°6, 48200 Durango, Spain.
Molecules (Basel, Switzerland)
|July 12, 2025
概括
在造厂的粘合剂系统中,无机替代品如酸和地聚合物显著减少了危险排放. 这项研究显示,与有机结合剂相比,BTEX和PAHs的减少超过90%,提高了安全性和可持续性.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 工业化学 工业化学 工业化学
背景情况:
- 造厂粘合器系统对于金属造至关重要,但可以释放危险的排放.
- 有机树脂 (性尿, furan,性-) 和粘土结合的绿色砂是传统的结合剂.
- 越来越需要可持续的替代品来最大限度地降低职业和生态风险.
研究的目的:
- 为了比较有机造厂粘合剂系统的危险排放与无机替代品.
- 量化挥发性有机化合物 (VOC),多环芳 (PAH) 和其他污染物的减少.
- 为酸和地聚合物结合剂的可行性提供经验证据.
主要方法:
- 在阿兹特兰基金会的试点工厂进行了受控的室内测试.
- 60公斤的铁合金件在110公斤的砂模中生产,使用均和异质的粘合剂配置.
- 气体提取系统和专用仪器测量了VOC,PAH,,颗粒物和热解气体.
主要成果:
- 与有机结合剂相比,无机结合剂 (酸,地质聚合物) 实现了BTEX>90%的减少和PAH>94%的减少.
- 气体排放量显著减少:CO (>30%),NOx (>98%) 和SO2 (>75%).
- 使用无机结合剂的均质和异质系统证明了大量的排放控制.
结论:
- 酸和地聚合物粘合剂为传统有机粘合剂提供了可持续和有效的替代品.
- 这些无机结合剂显著降低了金属造中的危险排放和优先污染物.
- 这些发现支持采用无机结合剂,以减少造厂的职业和环境影响.
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