基于材料组成的水泥糊的质行为构成模型
Chunming Lian1,2, Xiong Zhang1, Lu Han2
1Key Laboratory of Advanced Civil Engineering Materials of Education Ministry, School of Material Science and Technology, Tongji University, 4800 Cao'an Road, Shanghai 201804, China.
Materials (Basel, Switzerland)
|July 12, 2025
概括
一个新的模型使用颗粒性质预测水泥糊的风质,改进了混凝土混合物设计. 它准确地预测了各种配方的产量应力和粘度,有助于开发先进的混凝土应用.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 类风病学 类风病学 类风病学
背景情况:
- 混凝土糊的整形学对于新鲜混凝土的性能,如可加工性和均性至关重要.
- 现有的风学模型无法准确地捕捉复杂的水泥系统行为 (花,水化),并依赖于难以测量的参数.
- 这限制了学模型在混凝土技术中的实际应用.
研究的目的:
- 开发一种基于构成的新型构成模型,用于预测水泥糊的类型学.
- 使用虚拟最大包装分数 (φmax) 结合粒子间花和被困水效应.
- 为了实践预测,建立粉末特性和风湿学参数之间的定量联系.
主要方法:
- 在一个构成模型中引入了一个虚拟的最大包装分数 (φmax).
- 粉末特征 (颗粒大小,特定表面积) 与风湿学参数 (产量应力,塑料粘度) 具有定量相关性.
- 验证了该模型与65种不同的制剂配方,包括带有不同添加剂和超级可塑剂含量的普通和混合系统.
主要成果:
- 实现了高预测准确度:R2>0.98对于平面面粉,R2>0.85对于混合系统.
- 通过修改 φmax.成功地捕获了超级可塑剂的影响.
- 证明了模型的强度和参数效率.
结论:
- 开发的基于构成的模型准确地从基本的材料特性预测水泥糊的整形学.
- 这种框架使得物理可解释和可测量的预测成为可能,克服了经典模型的局限性.
- 在先进的混凝土应用中为智能混合设计提供了有价值的工具,例如自结合和3D打印混凝土.
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