用化修改的布鲁基酸水泥的性能和反应机制
Yueping Chen1, Daxing Zhou1, Xiaolong Liu2
1China Railway Construction Group Co., Ltd., Beijing 100040, China.
Materials (Basel, Switzerland)
|July 12, 2025
概括
将化 (AC) 添加到基于brucite的酸水泥 (BMPC) 中,可以优化定时间和强度. 最佳的4%的AC剂量增强了水分,改善了低碳应用的BMPC性能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 建筑材料 建筑材料
背景情况:
- 基于矿的酸水泥 (BMPC) 为传统水泥提供了一个低碳的替代品.
- 控制BMPC的设置时间和强度发展对于其实际应用至关重要.
- 对BMPC属性的协同调节仍然是一个挑战.
研究的目的:
- 调查化 (AC) 对BMPC的水化行为和性能的影响.
- 阐明AC影响设置时间,流动性和压力强度的机制.
- 为了确定最佳的AC剂量,以实现卓越的BMPC性能.
主要方法:
- 设置时间,流动性和压力强度的实验测试.
- 在水化过程中监测pH值和离子度.
- 使用X射线衍射 (XRD),热重力测量分析 (TG) 和入孔测量 (MIP) 的微结构分析.
主要成果:
- 通过4%的交流剂达到最佳性能,设置时间为16分钟,流动性为120毫米,28天的压力强度为54.5MPa.
- 发现AC可以抑制化合物的溶解,并减缓水合反应动力学.
- 经过适当的交流添加,观察到优化的孔隙结构和改善的压力强度.
结论:
- 化作为BMPC的设置时间和强度的有效调节器.
- 该机制涉及减缓水合反应和优化矩阵微观结构.
- 这种基于brucite的BMPC系统为酸水泥开发提供了可持续的低碳途径.
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