阿贡粘度的参考相关性 阿贡粘度的参考相关性
Sofia G Sotiriadou1, Konstantinos D Antoniadis2, Marc J Assael1
1Laboratory of Thermophysical Properties and Environmental Processes, Chemical Engineering Department, Aristotle University, 54636 Thessaloniki, Greece.
概括
提出了粘度的新参考相关性,提高了气相和液相的准确性. 这种相关性整合了先进的计算和实验数据,以实现更广泛的适用性和减少不确定性.
科学领域:
- 热力学是一种热力学.
- 流体动力学 流体动力学
- 材料科学 材料科学 材料科学
背景情况:
- 准确的粘度数据对于热力学建模和工程应用至关重要.
- 现有的粘度相关性在准确性和范围上有局限性.
- 在初始计算和实验测量方面最近的进展为改善相关性提供了机会.
研究的目的:
- 开发一种新的,广泛的对的粘度的参考相关性.
- 为了整合最近的初始稀释气体计算和批判性评估的实验数据.
- 为了提供与高精度的赫尔姆霍尔茨状态方程相容的相关性.
主要方法:
- 纳入最近的初始稀释气体计算.
- 对的实验粘度数据的批判性评估和整合.
- 在广泛的温度和压力范围内开发有效的参考相关性.
主要成果:
- 新的相关性提供了显著改善的不确定性,例如,0.076%的气体在0-0.1MPa和202-394K.
- 一个零密度的相关性与0.12%的不确定性是有效的84K到10,000K.
- 不确定性在中等压力下为1-2%,在高压/高温区域高达10%,在液态阶段为3%.
结论:
- 开发的粘度相关性代表了准确性和适用性的重大进步.
- 相关性适用于在各种条件下使用高精度状态方程.
- 这项工作为涉及的科学和工业应用提供了可靠的参考.
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