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Updated: Sep 15, 2025

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Published on: August 22, 2018

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在溶液和固体状态下,提奥芬和提亚替代的循环亚齐里丁的光色特性

Cristina Cu Castillo1, Jyotishka Nath1, Fernando Montalvillo Ortega1

  • 1Department of Chemistry and Biochemistry, University of Texas at Dallas, Richardson, Texas 75080, United States.

ACS omega
|July 14, 2025
PubMed
概括

基于双循环亚齐里丁衍生物 (DABH) 与烯和醇结合的新光色材料在固态中显示出增强的性能. 这些DABH化合物具有显著更长寿命的光色状态,使其在光电子领域的潜在应用成为可能.

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the...
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Removing one hydrogen from the intervening CH2 group...
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