在LA-ICP-MS中研究气体和颗粒碳在两相样本运输中的灵敏度差异
Lukas Brunnbauer1, David Ken Gibbs1, Detlef Günther2
1TU Wien, Institute of Chemical Technologies and Analytics Getreidemarkt 9/164 1060 Vienna Austria lukas.brunnbauer@tuwien.ac.at.
Journal of analytical atomic spectrometry
|July 14, 2025
概括
碳不是可靠的内部标准,用于基于碳的样品的激光除-诱导合等离子体质谱 (LA-ICP-MS) 分析. 颗粒和气态碳物种之间的灵敏度差异差异很大,这使得它不适合精确的元素分析.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
- 地质化学 地质化学
背景情况:
- 激光切除-诱导合等离子体质谱法 (LA-ICP-MS) 是固体元素分析的一个关键技术.
- 在LA-ICP-MS中,内部标准至关重要,以纠正矩阵效应和仪器漂移.
- 碳是基于碳的样品的逻辑内部标准,但由于二相运输,它的使用受到争议.
研究的目的:
- 在LA-ICP-MS期间量化颗粒物和气态碳物种之间的灵敏度差异.
- 评估碳作为碳基样本的内部标准的适用性.
主要方法:
- 使用LA-ICP-MS.去除五种不同类型的聚合物.
- 对废弃碳物种 (颗粒和气体) 两相运输的分析.
- 使用质量平衡计算气态碳的灵敏度和估计颗粒碳的灵敏度.
主要成果:
- 气态碳物种的灵敏度被确定为13.8 cts/pg.
- 在不同聚合物矩阵中,颗粒碳物种的灵敏度有显著差异 (1.6914.06 cts/pg).
- 对于颗粒碳的灵敏度差异可能高达7的系数,表明矩阵依赖.
结论:
- 在LA-ICP-MS期间,碳的颗粒形式呈现出取决于矩阵的灵敏度变化.
- 气态和颗粒碳物种之间的显著灵敏度差异证实了其作为内部标准的不足.
- 研究结果强烈建议不要将碳作为LA-ICP-MS碳质材料分析的内部标准.
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