在三重多孔系统中解读溶液和反应运输:雕刻岩石核心实验和数值建模.
Charles Soucey1, Collin Sutton2, Weipeng Yang1
1University of Minnesota - Twin Cities, Department of Earth and Environmental Sciences, 116 Church Street SE, Minneapolis Minnesota 55455, United States.
Environmental science & technology
|July 14, 2025
概括
了解三重性系统中的溶液运输是至关重要的. pozitron发射断层扫描 (PET) 图像显示了这些复杂的地下环境中的流速和断裂孔径如何影响溶液交换和反应性.
科学领域:
- 地质科学 地质科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 在三重多孔系统 (管道,裂,岩层) 中的溶解物和反应物运输对于地下应用至关重要.
- 系统的异质性和溶液交换导致异常运输,如早期到达和长时间的停留时间.
- 直接观察地下运输机制仍然是一个重大挑战.
研究的目的:
- 直接可视化和理解三重性系统中的溶液运输机制.
- 为了研究流量和断裂孔对溶液交换和反应性的影响.
- 阐明不同流量条件对溶液和矿物沉物分布的影响.
主要方法:
- 用于反应式运输实验的控制几何的雕刻的多洛石芯.
- 采用正电子发射断层扫描 (PET) 成像,用于直接可视化溶解物运输.
- 进行了数值模拟,以分析断裂孔径效应和流动动力学.
主要成果:
- 流速显著控制管道和断裂/矩阵之间的溶液交换.
- 在不同流动惯性下,PET成像和实验显示出不同的溶液/沉分布.
- 数字模拟证实了断裂孔在调节交换中的作用,并确定了3D循环区域,以提高更高流速的反应性.
结论:
- 鉴定器突破曲线可以由于增加交换而表现出多峰值模式.
- 蚀刻核心实验,PET成像和模拟的综合方法增强了对三重孔隙介质中的反应运输的理解.
- 研究结果提供了对由复杂的孔隙结构和流动动力学影响的地下过程的关键见解.
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