回复关于"相变原体中的化学结合"的评论
P C Müller1, S R Elliott2, R Dronskowski1
1Lehrstuhl für Festkörper- and Quantenchemie, Institut für Anorganische Chemie, RWTH Aachen University, D-52056 Aachen, Germany.
概括
这项研究驳斥了那些说相变素化键是缺电子的说法. 电子计数规则证实GeTe债券富含电子,而不是多中心,挑战以前的解释.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 计算化学计算化学
背景情况:
- 在相变焦化物 (例如,GeTe) 中对化学结合赋值的批评.
- 之前的工作建议富含电子 ("高价") 结合.
- 评论员提出了 (GeTe) 1-x ((Sb2Te3) x晶体的缺电子和多中心结合模型.
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