在二极力场下超冷液体的流动
1Graduate School of Arts and Sciences, University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan.
The Journal of chemical physics
|July 15, 2025
概括
超冷液体表现出动态异质性,导致它们在施加力附近比纳维埃-斯托克斯方程预测的更快地流动. 这种偏差随着超级冷却的增加和动态异质性的增长而加剧.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 流体动力学 流体动力学
- 计算材料科学科学 计算材料科学
背景情况:
- 超冷液体的粘度随着温度下降而增加,导致玻璃过渡.
- 动态的异质性,以运动中的空间相关性为标志,伴随着这种过渡.
研究的目的:
- 调查动态异质性对超冷液体纳维埃-斯托克斯方程适用性的影响.
- 为了确定纳维埃-斯托克斯方程是否准确地描述了外力作用下的超冷液体中的流体流动.
主要方法:
- 采用分子动力学模拟用于二维超冷液体.
- 将局部双极力场应用于液体.
- 将模拟的稳定速度场与纳维埃-斯托克斯预测进行了比较.
主要成果:
- 在真实空间中观察到纳维埃-斯托克斯方程的显著分解.
- 超冷液体在施加力附近的流动速度比纳维埃-斯托克斯预测的要快.
- 这种偏差随着超冷的增加而放大,并与日益增长的动态异质性相关.
结论:
- 纳维埃-斯托克斯方程不足以描述超冷液体的流动,特别是在外力下.
- 动态异质性在偏离纳维埃-斯托克斯预测方面发挥着至关重要的作用.
- 需要进一步的研究来了解超冷液体复杂的流动动力学.
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