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Updated: Sep 15, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

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容易和绿色合成[Pd(NHC) ((η3-R-allyl) Cl]复合物及其抗癌活性

Riku Saito1, Pierre Arnaut1, Benon Maliszewski1

  • 1Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium. steven.nolan@ugent.be.

Dalton transactions (Cambridge, England : 2003)
|July 16, 2025
PubMed
概括

一种新的,环保的-N-异环碳 (NHC) 复合物的合成产生了强大的抗癌剂. 这些新型化合物显示出显著的细胞毒性,在耐药癌症模型中表现优于西斯.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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