活跃的布朗粒子的二进制混合物具有明显的非零活动
Nicholas J Lauersdorf1, Ehssan Nazockdast1, Daphne Klotsa1
1Department of Applied Physical Sciences, University of North Carolina at Chapel Hill, USA. ehssan@email.unc.edu.
Soft matter
|July 17, 2025
概括
有不同速度的活跃布朗粒子的混合物表现出独特的行为. 我们发现了三种不同的模式,具有微相分离和大波动,为复杂的活性物质系统提供了洞察力.
科学领域:
- 活动物质物理学 活动物质物理学
- 软的凝聚物质是软的凝聚物质.
- 统计力学就是统计力学.
背景情况:
- 活跃的布朗粒子 (ABP) 是自行实体的基本模型.
- 在ABPs中,运动诱导相分离 (MIPS) 会导致新兴的集体行为.
- 不同活动的ABP混合物较少被探索,但与不同的系统相关.
研究的目的:
- 研究具有不同活动的活性布朗粒子二进制混合物的稳定态行为.
- 探索由活动比率调节的出现性质和相位行为.
- 揭示了驱动观察到的宏观现象的潜在微观机制.
主要方法:
- 对活性布朗粒子悬浮物的计算研究.
- 慢粒子和快粒子之间的活动比率 (Pe^R) 的系统变化.
- 对宏观性质 (密度,压力) 和微观域结构的分析.
主要成果:
- 根据活动比率确定了三个不同的模式,其特点是基于独特的新兴行为.
- 观察到宏观性质的非单调性行为,随着活动比的变化.
- 发现了微相分离,增加了界面波动和显著的雪崩事件.
结论:
- 活动比率是一个关键参数,它决定了二进制ABP混合物的出现行为.
- 同时变化的活动揭示了单分散系统中看不到的复杂现象.
- 这项工作为理解和设计具有可调节性质的活性物质系统提供了基础.
相关概念视频
Colloids and Suspensions
2.4K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
2.4K
¹H NMR: Complex Splitting
1.4K
A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
1.4K
Mass Spectrometry: Complex Analysis
898
Mass spectrometry is an important technique for the identification of pure compounds. However, it has some limitations for the analysis of complex mixtures, often due to excessive fragmentation making the spectrum too complicated to decipher. Mass spectrometry can be combined with suitable separation methods in sequence, forming hyphenated methods, which are useful in the analysis of complex mixtures.
GC–MS is a powerful hyphenated method commonly used in forensics and environmental...
GC–MS is a powerful hyphenated method commonly used in forensics and environmental...
898
Classifying Matter by Composition
79.4K
Matter: Pure Substances and Mixtures
According to its composition, the matter can be classified into two broad categories — pure substances and mixtures.
A pure substance is a form of matter that has a constant composition throughout with uniform properties. For example, any sample of sucrose has the same composition and same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
A mixture is composed of two or...
According to its composition, the matter can be classified into two broad categories — pure substances and mixtures.
A pure substance is a form of matter that has a constant composition throughout with uniform properties. For example, any sample of sucrose has the same composition and same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
A mixture is composed of two or...
79.4K
Ion Exchange
667
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
667
Thermodynamics: Activity Coefficient
2.0K
Activity is the measure of the effective concentration of the species in solution. It can be expressed as the product of the molar concentration of the species and its activity coefficient. The activity coefficient is a dimensionless quantity and depends on the total ionic strength of the solution.
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
2.0K


