重新定义溶剂电阻:在纳米封闭聚合物中,溶剂表面相互作用的主导作用
Trevor R Devine1, Robert A Riggleman1, Daeyeon Lee1
1Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
我们开发了聚合物纳米复合材料,通过将聚合物透到纳米粒子结构中,增强了耐溶剂的性能. 溶剂-表面相互作用,而不仅仅是聚合物-溶剂亲和力,是防止聚合物溶解的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术纳米技术
背景情况:
- 基于聚合物的材料往往表现出较差的溶剂抵抗,导致胀,变形和溶解.
- 现有的材料在暴露于攻击性溶剂时,难以保持完整性.
研究的目的:
- 为了提高聚合物材料的耐溶剂性.
- 研究纳米颗粒-溶剂相互作用在纳米复合材料中的聚合物保留中的作用.
主要方法:
- 聚合物透到密集的纳米粒子间隙中.
- 分析基于聚合物-溶剂和溶剂-纳米粒子相互作用的聚合物去除.
- 调节纳米粒子表面化学,限制尺度和聚合物身份.
主要成果:
- 聚合物纳米复合材料 (PINFs) 显示出显著增强的溶剂耐受性,即使对抗好的溶剂.
- 发现溶剂-纳米颗粒相互作用在取代吸附聚合物链的过程中至关重要.
- 对纳米颗粒表面具有更强的溶剂亲和力,促进了聚合物位移,取代了聚合物-溶剂热力学.
结论:
- 溶剂-表面相互作用是工程强大的聚合物纳米复合材料的关键,被忽视的参数.
- 聚合物吸附,封闭和溶剂表面亲和力的相互作用决定了溶剂电阻.
- 这种方法可以创建聚合物纳米复合材料,在强烈的溶剂暴露下保留聚合物含量.
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