通过亚磁脱磁制冷实现的低于30mK的温度
Qiao-Fei Xu1, Xin-Yang Liu2, Ruo-Tong Wu1
1State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.
Journal of the American Chemical Society
|July 17, 2025
概括
使用KYb3F10的亚磁脱磁制冷 (ADR) 实现了低于50mK的超低温度. 这种新型制冷剂的磁变化明显高于商业选择,克服了一个关键的设计挑战.
科学领域:
- 低温技术
- 凝聚物质物理学
- 材料科学
背景情况:
- 对于超低温研究来说,亚磁脱磁制冷 (ADR) 是必不可少的,但由于制冷剂的性能而受到限制.
- 现有的制冷剂难以实现大磁变化 (-ΔSm) 和低订单温度 (T0).
研究的目的:
- 开发一种新的磁性制冷剂,克服ADR中的-ΔSm和T0限制.
- 展示一种能够高效地达到超低温度的材料.
主要方法:
- 将弱磁交换和双极相互作用纳入被挫败的磁体KYb3F10.
- 描述磁性特性并进行ADR测试.
主要成果:
- KYb3F10具有很大的-ΔSm,比商业制冷剂高出219%.
- 该材料表现出低于50mK的订制温度 (T0).
- 实际的ADR测试达到27.2mK的最低温度.
结论:
- KYb3F10是用于超低温ADR的高性能制冷剂.
- 这项工作解决了长期以来设计具有大-ΔSm和低T0的磁性制冷剂的挑战.
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