化学压力诱导的高效载体度优化用于SmS中的高热电性能
Huijun Liao1, Qihong Xiong2, Zizhen Zhou3
1State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing 400030, P. R. China.
The journal of physical chemistry letters
|July 18, 2025
概括
在SmS中通过Y兴奋剂引入局部化学压力,可显著提高载体度和热电性能. 这种新的方法在1023 K时实现了1.65 mW m-2 K-2的创纪录功率系数.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 热电学是一种热电学.
背景情况:
- 载体度对于优化热电材料至关重要.
- 传统的有价兴奋剂在调节载体度方面存在局限性.
- 硫化 (SmS) 是一个有前途的n型热电材料,具有混合价值状态.
研究的目的:
- 探索一种用于调节热电材料中载体度的新策略.
- 调查局部化学压力对SmS中载体度的影响.
- 通过有针对性的兴奋剂来增强SmS的热电性能.
主要方法:
- 通过用不同元素对SmS进行化,引入局部化学压力.
- 比较Y兴奋剂与Sc兴奋剂在载体度上的疗效.
- 分析由Y兴奋剂诱导的Sm价值状态的变化.
- 在高温下测量热电功率系数.
主要成果:
- 在同等度下,Y兴奋剂提供的电子数量是Sc兴奋剂的6-12倍.
- Y兴奋剂诱导了显著的局部化学压力,改变了Sm价值从2+到3+.
- 这种价值变化导致载体度大幅增加.
- 创纪录的峰值功率系数为1.65 mW m-2 K-2 在1023 K时实现,用于Y化SmS.
结论:
- 局部化学压力是调整混合价值化合物中载体度的有效策略.
- 在SmS中Y注提供了一种高效的方法来增强热电特性.
- 这项工作为设计含有混合价值元素的高性能热电材料提供了新的见解.
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