复合火箭推进剂的有效性能修改通过循环胺的凝聚物
Veerabhadragouda B Patil1,2, Rafał Lewczuk2, Filip Sazeček1
1Institute of Energetic Materials, Faculty of Chemical Technology, University of Pardubice, Pardubice CZ-532 10, Czech Republic.
新的燃烧调节剂cis-1,3,4,6-tetranitrooctahydroimidazo-[4,5-d]-imidazole (BCHMX) 对推进剂燃烧速度产生了积极的影响,特别是当它作为凝聚物 (CAC) 替代甲 (AP) 时. 这项研究详细介绍了它对推进剂特性的影响.
科学领域:
- 推进剂燃烧化学和能量材料科学.
- 固体火箭推进剂的配方和性能评估.
背景情况:
- 甲 (AP) 是复合推进剂中常见的氧化剂.
- 寻求新型燃烧调节剂以提高推进剂性能和安全性.
- cis-1,3,4,6-tetranitrooctahydroimidazo-[4,5-d]-imidazole (BCHMX) 是一种新的燃烧修饰剂.
研究的目的:
- 研究用BCHMX基配方代替甲 (AP) 对推进剂特性的影响.
- 分析BCHMX含量与推进剂特性 (如燃烧速度,点火温度和灵敏度) 之间的关系.
- 描述HMX/BCHMX凝聚物 (CAC) 的结构.
主要方法:
- 制备具有不同重量百分比 (10,20,30 wt %) 的AP替代HMX,机械混合物 (PM) 和HMX/BCHMX凝聚物 (CACs) 的推进剂.
- 使用粉末X射线衍射,FTIR和拉曼光谱仪对CAC的表征.
- 推进剂燃烧速率,燃烧热量 (Qc),点火温度,热分解速率,冲击灵敏度,硬度和特定冲动的测量.
主要成果:
- 证实CACs是共晶β-HMX/BCHMX与多余β-HMX的混合物.
- 增加CAC含量降低了推进剂的压力指数,与纯HMX或PM不同.
- 观察到CAC对燃烧速率有显著的积极影响,特别是在20重%的AP替代时.
结论:
- BCHMX,特别是在CAC形式,是HMX/HTPB/AP推进剂的一个有前途的燃烧修饰剂.
- CAC提高燃烧速度,降低压力指数,提供更好的推进剂控制.
- 需要进一步研究燃烧特性和灵敏度之间的关系.
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