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相关概念视频

Nomenclature of Alkynes02:39

Nomenclature of Alkynes

19.2K
Alkynes are unsaturated hydrocarbons characterized by the presence of carbon-carbon triple bonds and have a general formula CnH2n-2. The nomenclature of alkynes follows a set of rules similar to alkanes and alkenes; however, alkynes bear the suffix "-yne" instead of "-ane" or "-ene." There are two approaches to naming alkynes:
19.2K
Structure of Conjugated Dienes01:16

Structure of Conjugated Dienes

5.9K
Introduction
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
5.9K
Nomenclature of Alkenes02:29

Nomenclature of Alkenes

13.0K
The IUPAC naming system for alkenes replaces -an- with -en- in the corresponding parent alkanes. Accordingly, a simple alkene replaces the -ane suffix of the alkane with -ene.
As per the IUPAC rules, the longest carbon chain containing the maximum number of double bonds is identified as the parent chain and is numbered such that the doubly bonded carbon atoms receive the lowest possible numbers. The location of the double bond is indicated by the number of its first carbon atom. In branched...
13.0K
Structure and Bonding of Alkenes02:47

Structure and Bonding of Alkenes

17.8K
Olefins, which are unsaturated hydrocarbons containing one or more carbon–carbon double bonds, are broadly divided into alkenes and cycloalkenes. The general chemical formula of an alkene is CnH2n.
Doubly bonded carbons are sp2 hybridized and have a trigonal planar geometry. The double bond is composed of a σ bond formed by the overlap of hybrid orbitals and a π bond produced by the lateral overlap of unhybridized 2p orbitals on both the carbons. Each carbon atom is...
17.8K
Structure and Physical Properties of Alkynes02:37

Structure and Physical Properties of Alkynes

11.5K
Introduction:
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The...
11.5K
Structure and Nomenclature of Ethers02:28

Structure and Nomenclature of Ethers

12.5K
Structure and Bonding
Ethers are organic compounds with an ether functional group which is characterized by an oxygen atom connected to two — identical or different — alkyl, aryl, or vinyl groups. The C–O–C linkage in dimethyl ether — the simplest ether — has an approximately tetrahedral bond angle of 110.3 degrees. The oxygen atom is sp3- hybridized, with the C–O distance being about 140 pm.
Classification of Ethers
Based on their attached substituent...
12.5K

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相关实验视频

Updated: Sep 14, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

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N-亚利乙烯折叠材料:结构和功能

Seungwon Lee1, Geunmoo Song2, Kyu-Sung Jeong1

  • 1Department of Chemistry, Yonsei University, Seoul 03722, Republic of Korea.

Accounts of chemical research
|July 22, 2025
PubMed
概括

芳香折叠体模仿生物宏分子,形成用于分子识别的螺旋结构. 最近的进步包括可调整的基于印洛卡巴索尔的折叠体和用于选择性客结合和刺激响应转换的imini链接系统.

科学领域:

  • 超分子化学 超分子化学
  • 有机化学 有机化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 蛋白质和核酸是合成生物巨分子的灵感来源.
  • 芳香折叠分子是合成分子,折叠成稳定的二级或更高阶结构.
  • N-烯-乙烯折叠体,以交替的烯异环和乙键为特征,形成具有内部空洞的螺旋结构.

研究的目的:

  • 审查N-乙烯乙烯折叠材料的开发和应用.
  • 要突出控制折叠机稳定性和螺旋手的设计原则.
  • 展示折叠体在分子识别,传感和动态材料开发中的使用.

主要方法:

  • 合成N-烯乙烯折叠体与不同的烯异环.
  • 利用动态共价化学和客人导向合成来进行同体体折叠体构造.
  • 调查foldamer复合体的客结合特性和刺激响应行为.

主要成果:

  • 印洛卡巴索尔 - 皮里丁 (IP) 折叠体允许调节折叠稳定性和螺旋手性,用于离子识别.
  • 具有较大的空腔的印洛卡巴佐尔-纳菲尔胺 (IN) 折叠体结合单糖类,如葡萄糖.
  • 带有固定螺旋腔的同体基质折叠体表现出基质客体的选择性结合.

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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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相关实验视频

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Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides
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Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides

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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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  • 胺基结合的折叠体与特定的糖形成2:2复合体,显示温度依赖的客户端切换和域交换组件.
  • 结论:

    • 芳香折叠剂为创建具有定制功能的复杂分子架构提供了多功能平台.
    • 折叠分子化学可以设计用于选择性分子识别,传感和动态材料应用的系统.
    • 未来的方向包括开发智能材料,类似酶的催化剂和生物适用折叠材料.