调节抗热和度火,以增强二氧化排放
Wasim Ullah Khan1,2, Haris Zaman2, Waheed Ullah Khan1
1Analysis and Testing Center, Shenzhen Technology University/College of new Materials and new Energies, Shenzhen Technology University, Pingshan, Shenzhen, 518118 P.R. China. zhuhaiou@sztu.edu.cn.
新的Sr3LaAl3B4O15合Tm3+和Dy3+的光剂显示出优异的热稳定性和白色LED的颜色一致性. 这些材料有效地抑制热灭和度灭,可用于可靠的固态照明应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的阴影是什么意思
背景情况:
- 热灭 (TQ) 效应在高温下降低光的亮度,影响光输出稳定性.
- 在CIE图中,颜色一致性对于温度耐受性至关重要,在研究中经常被忽视.
- 开发具有高热稳定性和一致色彩输出的光剂对于先进的照明是必不可少的.
研究的目的:
- 为了研究Tm3+和Dy3+合的Sr3LaAl3B4O15 (SLAB) 作为潜在的白光发射材料.
- 为了评估这些新的热稳定性和颜色一致性.
- 了解有助于抗TQ行为和抑制度火的能量转移机制.
主要方法:
- 合成和全面的特征 Tm3+ 和 Dy3+ 杂的 SLAB .
- 使用的技术:X射线衍射,瑞特维尔德精细化,TEM,SEM,ESR和分散反射光谱学.
- 分析Tm3+和Dy3+离子之间的能量转移 (ET) 调制.
主要成果:
- 观察到有效的抗TQ行为和由于Tm3+和Dy3+之间的ET调制导致的度火的内在抑制.
- 通过电偶极相互作用实现了高ET效率 (78.28%),并证明了高Tm3+兴奋剂的可行性.
- 证明了优越的热稳定性,具有高的反TQ性能 (105.8%在400K) 和低的色变化 (ΔEs = 10.31 × 10−3).
结论:
- 用Tm3+和Dy3+合的SLAB光体表现出增强的光发光和出色的热稳定性,性能优于典型的Ln3+离子行为.
- 这些光体显示出有希望的抗TQ性能和颜色稳定性,与商业光体相美.
- SLAB:Tm3+,Dy3+合物适用于温暖白色LED应用,提供高颜色染 (Ra ≥86.4) 和稳定的输出.
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