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相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

14.8K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.8K
Structures of Solids02:22

Structures of Solids

14.8K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
14.8K
Metallic Solids02:37

Metallic Solids

18.7K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.7K
Lattice Centering and Coordination Number02:33

Lattice Centering and Coordination Number

9.9K
The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
9.9K
Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

13.2K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
13.2K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.6K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.6K

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相关实验视频

Updated: Sep 14, 2025

Determining the Ice-binding Planes of Antifreeze Proteins by Fluorescence-based Ice Plane Affinity
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Determining the Ice-binding Planes of Antifreeze Proteins by Fluorescence-based Ice Plane Affinity

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在质子排序的六角冰中基底位移.

Michael J Demkowicz1

  • 1Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77843, USA.

The Journal of chemical physics
|July 23, 2025
PubMed
概括

六角冰中的质子排序并没有缓解脱位滑动. 分子动力学揭示了特定的脱位保持静止,其中一些只在高应力下移动,影响了塑料流理论.

科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 计算化学计算化学

背景情况:

  • 六角冰 (冰I) 呈现出复杂的质子排序,特别是在低温阶段 (冰XI).
  • 脱位滑动是晶体固体 (包括冰) 中塑性变形的主要机制.
  • 了解脱位行为对于预测各种条件下冰的机械性质至关重要.

研究的目的:

  • 为了研究核心结构和关键解决的剪切应力,在质子排序的六角冰中进行基底位位滑动.
  • 为了确定不同类型的位移的移动性 (直线,扭曲,60°,螺丝) 在混合和滑动设置平面上.
  • 评估质子排序对易于排位运动的影响.

主要方法:

  • 用分子动力学 (MD) 模拟来建模脱位行为.
  • 分析的重点是核心结构和关键解决剪切应力 (CRSS) 的计算,用于位运动.
  • 模拟检查了六角冰格内的混合和滑动设置平面上的位移.

主要成果:

  • 大多数研究的脱位,包括螺旋和扭曲型,被发现是性的,需要高分辨率的剪切应力 (≥0.11) 来实现运动.
  • 直接的60°混合位移表现出不同的CRSS,取决于核心定向和加载方向.
  • 最低的观察到的模量正常化CRSS直线60°混合位移是0.044,相当于钻石中的皮尔尔斯屏障. 扭曲可以阻碍或减少这种压力到0.037.

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

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Last Updated: Sep 14, 2025

Determining the Ice-binding Planes of Antifreeze Proteins by Fluorescence-based Ice Plane Affinity
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Determining the Ice-binding Planes of Antifreeze Proteins by Fluorescence-based Ice Plane Affinity

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An Externally-Heated Diamond Anvil Cell for Synthesis and Single-Crystal Elasticity Determination of Ice-VII at High Pressure-Temperature Conditions
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An Externally-Heated Diamond Anvil Cell for Synthesis and Single-Crystal Elasticity Determination of Ice-VII at High Pressure-Temperature Conditions

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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  • 发现六角冰中的质子排序并不能促进脱位滑动.
  • 结论:

    • 质子排序并没有显著降低六角冰中基底位位滑动的能量屏障.
    • 大多数脱位的性质表明,在典型条件下,质子排列冰中的塑料流量有限.
    • 这些发现需要对现有的关于冰I和冰XI的塑性流动理论进行重新评估.