测量超高分子量聚乙烯固态复合材料的性
Peder C Solberg1, Igor Tsukrov2, Douglas W Van Citters1
1Dartmouth College, Hanover, NH, 03755, USA.
概括
这项对超高分子量聚乙烯 (UHMWPE) 纳米复合材料的研究表明,虽然性在较高碳黑负载下降,但疲劳抵抗性得到改善. 这突出了相分离聚合物复合材料中明显的故障行为.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 生物材料工程 生物材料工程
背景情况:
- 超高分子量聚乙烯 (UHMWPE) 的固态复合材料正在探索关节塑性应用.
- UHMWPE的高融粘度导致明显的相分离,可能会改变材料的行为不同于传统的微观结构因素,如交叉连接.
研究的目的:
- 量化UHMWPE纳米复合材料的抗故障能力,其中含有不同度的碳黑 (CB) 填充剂.
- 为了研究填充剂加载,相分离和机械性能之间的关系.
主要方法:
- 对UHMWPE-CB复合材料进行了拉伸,冲击性和疲劳裂纹传播阻力 (CPR) 测试.
- 使用扫描电子显微镜 (SEM) 和骨折表面成像进行了微结构分析.
主要成果:
- 拉力和冲击性最初在较低的CB负载下增加或保持,然后在较高的负载下降.
- 疲劳CPR在较低的CB负载下表现出类似的性趋势,但在较高度 (2.5-10 wt%) 中得到改善.
- 微观结构变化包括断裂模式,颗粒涂层和空隙形成的过渡,与机械性质变化相关.
结论:
- 拉伸和冲击性不是这些相分离的UHMWPE纳米复合材料中疲劳CPR的可靠指标.
- 这些发现表明UHMWPE复合材料在高负载应用中的潜力,并激励进一步研究结构-属性关系.
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