先进的核心盖结构的相变纤维膜用于灵活超级电容器的现场热调节
Zhi-Jun Zhu1, Guanhua Shen1, Akbar Bashir1
1Guangdong Provincial Key Laboratory of New Energy Materials Service Safety, Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518055, PR China.
Journal of colloid and interface science
|July 24, 2025
概括
本研究介绍了一种用于灵活超级电容器的新型相变纤维薄膜,提供了增强的热管理. 创新的设计确保了在极端温度下稳定的性能,提高了储能设备的可靠性.
科学领域:
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
- 纳米技术纳米技术
背景情况:
- 超级电容器在极端温度下降解,由于材料降解和电解质阻力增加,寿命和可靠性降低.
- 高效的温度调节对于在恶劣环境中稳定的超级电容器运行至关重要.
研究的目的:
- 开发一个灵活的超级电容器,具有增强的热管理能力.
- 在极端温度条件下克服超级电容器的局限性.
主要方法:
- 使用层层的同轴电制造核心-盖层相变纤维薄膜.
- 在现场聚合聚氨酸纳米阵列在金涂纤维膜基板上的聚合.
- 使用PVA/H2SO4凝电解质制造灵活的超级电容器.
主要成果:
- 灵活的超级电容器在5 mV s-1下实现了521.3 mF cm-2的面积电容,这是由于针状的聚氨酸纳米阵列增强了表面积和离子传输.
- 换相纤维在0~10°C和40~50°C范围内显示出高潜热 (62.4 Jg-1),可有效进行热调节.
- 在双相变换区域的稳定电容和内部电阻证实了强大的热管理.
结论:
- 开发的相变纤维薄膜为灵活的超级电容器提供了显著的热调节.
- 这一进步为在可变温度条件下运行的储能设备提供了更高的稳定性和可靠性.
- 这项技术在先进的能源存储中具有巨大的未来应用潜力.
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