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相关概念视频

Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

1.7K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
1.7K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.6K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.6K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.9K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.9K
Ionic Strength: Overview01:12

Ionic Strength: Overview

1.7K
The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution...
1.7K
Formation of Complex Ions03:45

Formation of Complex Ions

24.0K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
24.0K
Ionic Bonds00:42

Ionic Bonds

121.8K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
121.8K

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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在双分散固体电解质中增强离子导电性.

Vesselin I Yamakov1, April A Rains2,3, Jason S Packard2,4

  • 1Analytical Mechanics Associates, Hampton, Virginia 23666, United States.

The journal of physical chemistry. B
|July 28, 2025
PubMed
概括
此摘要是机器生成的。

研究人员探索了固体电解质,以获得更安全,更高容量的能量存储. 模拟显示,粗细颗粒的混合物显著提高固态电池的离子导电性,特别是在特定的颗粒大小比率和高颗粒边界导电性的情况下.

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 计算机建模 计算建模

背景情况:

  • 对于安全,高容量的储能需求的不断增长推动了对全固态电池的兴趣.
  • 固体电解质比传统的液体电解质提供了更好的安全性和耐用性.
  • 优化固体电解质中的离子导电性对于电池性能至关重要.

研究的目的:

  • 为了研究具有双分散颗粒大小的固体电解质的离子导电性.
  • 确定改善固体电解质中离子运输的最佳条件.
  • 了解混合颗粒大小电解质导电性改进背后的机制.

主要方法:

  • 利用粒子动力学电力学计算模型来模拟离子导电性.
  • 检查的电解质由粗细颗粒的混合物组成.
  • 使用不同颗粒大小的Li6PS5Cl固体电解质进行实验验证.

主要成果:

  • 模拟显示了增加的密度和离子导电性,其细颗粒含量为10-30%体积.
  • 高颗粒边界导电性 (≥批量导电性) 和颗粒大小比率>3对于增强至关重要.
  • 实验结果证实了对Li6PS5Cl电解质的模拟结果.

结论:

  • 两散粒大小的固体电解质可以显著提高离子导电性.
  • 优化颗粒尺寸分布和颗粒边界特性是高性能固态电池的关键.
  • 计算建模为设计先进的固体电解质材料提供了宝贵的工具.