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Updated: Sep 13, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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远距离支架灵活性调节耳环激活参数在Re(I) 替换反应:作为"主题第三协调球体"的动态情况

Alec T Larson1, Serhii Vasylevskyi1, Michael J Rose1

  • 1Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States.

Journal of the American Chemical Society
|July 29, 2025
PubMed
概括

金属复合体中的动态连接体支架显著提高了反应性. 这项研究表明,通过简化反应性研究,调整连接体灵活性提供了创建更具反应性的金属复合物的新设计原则.

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