非对称的三甲基化非化电子接收器,用于高效和稳定的有机太阳能电池
Yang Cheng1, Jianing Xu1, Shijie Liang1
1Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, P. R. China.
新的非聚合环电子受体 (NFREAs) 为有机太阳能电池 (OSC) 提供了具有成本效益的替代方案. 不对称的NFREA设计提高了分子刚性和设备性能,实现了16.11%的功率转换效率.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 有机太阳能电池 (OSC) 中的环电子受体 (FREA) 面临复杂合成和高成本的挑战.
- 非化环电子接受器 (NFREAs) 提供了一个更简单,更具成本效益的替代方案,但往往会损害设备的性能.
研究的目的:
- 合成和评估两种新型不对称的非化环电子受体 (NFREAs),即3TT-CF3和3TT-BCF3,用于高效的有机太阳能电池 (OSC).
- 调查不对称分子工程,特别是引入 (三甲基) 双替代剂对NFREA特性和OSC性能的影响.
主要方法:
- 两个不对称的NFREAs的模块化合成:3TT-CF3和3TT-BCF3.
- 使用合成的NFREAs和非化溶剂o-xylene制造OSC设备.
- OSC设备的性能特征,包括功率转换效率 (PCE),短路电流密度,填充因子和电压损失.
主要成果:
- 与3TT-CF3.3相比,3TT-BCF3 NFREA具有 (三甲基) 双替代剂,显示出增强的分子刚性,减少能量障碍和优化混合物形态,与3TT-CF3.3相比.
- 基于D18:3TT-BCF3的OSC设备实现了16.11%的功率转换效率 (PCE),超过了D18:3TT-CF3设备的15.41%.
- 3TT-BCF3设备的性能提升归因于更高的短路电流密度,更好的填充系数和更低的电压损失.
结论:
- 不对称的分子工程是为OSCs开发高性能NFREA的可行策略.
- 3TT-BCF3 NFREA为实现具有成本效益和效率的有机太阳能电池提供了一个有希望的途径.
- 开发的NFREAs表现出卓越的热和存储稳定性,高效的电荷传输,以及有利于OSC应用的形态.
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