在海底水热通风条件下使用天然电化学梯度的碳减排
Journal of the American Chemical Society
|July 29, 2025
概括
性热水孔可能通过促进能量代谢和碳固定来启动生命. 研究人员模拟了通风条件, 发现[Ni-]FeS矿物质可以催化古老的代谢途径中的关键步骤,
科学领域:
- 生命研究的起源
- 地质化学和生物化学
- 天体生物学
背景情况:
- 性热水孔 (AHV) 是生命起源的环境.
- 在AHV中的pH梯度可能先于细胞膜.
- 在早期代谢途径中,[Ni-]FeS矿物质被认为是金属酶的前体.
研究的目的:
- 在模拟的AHV条件下研究二氧化碳降解成甲酸盐和酸盐.
- 探索[Ni-]FeS矿物质在伍德-Ljungdahl (WL) 路径的关键阶段的催化作用.
- 确定矿物成分,温度和电流对二氧化碳减排的影响.
主要方法:
- 使用一个模仿水热烟形成的宏观反应器.
- 使用实验模拟和电化学技术.
- 使用复制自然热水过程的协议合成矿物质.
主要成果:
- 成功检测了WL路径的两个关键步骤:二氧化碳到酸和酸的形成.
- 证明[Ni-]FeS矿物质,特别是含有Ni的矿物质,催化这些反应.
- 在10纳米安培至10微安培的电流下显示有效的二氧化碳减排,受矿物质类型和温度的影响.
结论:
- 与[Ni-]FeS矿物质的AHV接口为原代谢能量转导和碳固定提供了可行的环境.
- 这些发现支持早期地球环境中的无机矿物催化剂促进了生物代谢的出现的假设.
- 这项研究突出了外星通风系统中电化学驱动的原始代谢的潜力.
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