基于固体废物的含有剩余石膏的高贝莱特硫氨酸水泥在高温反应动力学的研究
Dunlei Su1,2, Mingxin Yang1, Yani Hao1
1School of Civil Engineering, Shandong Jiaotong University, Jinan 250357, China.
Materials (Basel, Switzerland)
|July 30, 2025
概括
这项研究揭示了新型水泥的高温反应动力学,详细说明了矿物质的形成和消耗. 调查结果有助于优化低碳水泥生产和矿物成分控制.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 地质化学 地质化学
背景情况:
- 在水泥生产中利用固体废物对于可持续性至关重要.
- 了解新型水泥材料的高温反应动力学对于过程优化至关重要.
- 新型高贝莱特硫酸水泥 (NHBSAC) 与残余石膏的特殊矿物学需要详细的动力分析.
研究的目的:
- 阐明NHBSAC泥中的高温反应过程和矿物形成规律.
- 建立关键矿物质的高温反应动力学模型.
- 为了确定控制矿物质形成和消耗的激活能量.
主要方法:
- 使用定量X射线衍射 (QXRD) 分析来描述矿物相.
- 数字拟合方法被用来建立矿产形成和消耗的动力模型.
- 在各种化系统下进行了动态分析,以确定反应机制和激活能量.
主要成果:
- 随着保持时间和温度的增加,C4A3S ̄ (ye'elimite) 和β-C2S (belite) 的形成增加,而CaSO4 (剩余石膏) 则被消耗.
- 在固态反应控制下,矿物质的形成和消耗遵循动态方程.
- C4A3S ̄和β-C2S形成是扩散控制的 (D4方程),CaSO4消耗是接口反应控制的 (R3方程). 激活能量随着温度范围的变化而显著变化.
结论:
- 该研究提供了NHBSAC块形成的定量动力模型.
- 了解这些动力学可以灵活地控制矿物成分.
- 这项研究为低碳水泥制备和优化矿物设计提供了理论基础.
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