对煤矿气体的红外光谱学定量分析方法的研究
Feng Zhang1, Yuchen Zhu1, Lin Li1
1Electronic Information Engineering, Xi'an Technological University, Xi'an 710021, China.
Molecules (Basel, Switzerland)
|July 30, 2025
概括
本研究介绍了一种先进的富里埃变换红外光谱法 (FTIR) 方法,用于准确检测煤矿气体. 该技术有效地纠正光谱漂移并量化各种气体,确保矿山安全.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 环境监测 环境监测
背景情况:
- 精确的煤矿气体检测对于生产安全至关重要.
- 福利埃变换红外光谱 (FTIR) 提供了敏感的,非破坏性的在线监测能力.
- 地下环境带来了诸如光谱基线漂移和复杂气体混合等挑战.
研究的目的:
- 开发和验证使用FTIR的煤矿气体的定量分析方法.
- 为了应对光谱漂移和复杂气体混合物的重叠吸收峰值的挑战.
- 提高煤矿在线气体分析的精度和可靠性.
主要方法:
- 应用的自适应平滑度参数对光谱基线校正的最小平方进行了惩罚.
- 根据吸收峰值特征 (明显与重叠) 分类的气体.
- 利用光谱线选择与曲线适合不同的峰值和一个可变的选择方法与反向传播神经网络重叠的峰值.
主要成果:
- 实现了多种气体的低检测极限 (例如,SF6的0.1ppm,C2H2的0.2ppm,CH4的0.5ppm).
- 所有分析的气体的量化限值低于10 ppm.
- 证明了高精度,绝对误差<0.3%,FS. 和相对误差<10%.
结论:
- 拟议的FTIR定量分析方法有效地检测和量化煤矿气体.
- 该方法显示了良好的预测性能,提高了煤矿运营中的安全性.
- 该技术为在具有挑战性的地下环境中进行在线监控提供了可靠的解决方案.
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