半环双极玻璃介电聚合物电容器用于高级高温电容储能器
Weibin Ren1,2, Hui Tong3, Shimo Cao3
1State Key Laboratory of New Ceramic Materials, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China.
Advanced materials (Deerfield Beach, Fla.)
|July 30, 2025
概括
研究人员开发了先进的半环双极玻璃介电聚合物 (sAl-DG),以克服高性能电容器的关键挑战. 这些新材料在极端温度下提供了特殊的能量密度和效率,为更小,更可靠的电子系统铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 电气工程 电气工程
背景情况:
- 高功率密度电容对于现代电气系统至关重要,要求具有高能量密度,效率和可靠性的介电材料.
- 现有的介电材料面临的挑战是:在玻璃过渡温度 (Tg) 时同时实现高带间隙 (Eg),在Eg时实现介电常数 (εr),在Tg时实现自愈.
研究的目的:
- 开发新型介电聚合物,将关键材料属性悖论解开,以提高电容器性能.
- 创建适合在高温和极端电场下运行的超高功率密度电容器的材料.
主要方法:
- 半非环形双极玻璃介电聚合物 (sAl-DG) 的合成,其中具有交替的非结合的环形和双极芳香单元.
- 描述sAl-DG聚合物的关键性质,包括带隙 (Eg),玻璃过渡温度 (Tg),介电常数 (εr) 和自我愈合能量.
- 在苛刻的操作条件下使用sAl-DG介电材料制造和测试堆叠电容器.
主要成果:
- 开发的sAl-DG聚合物具有很大的Eg (3.99-4.26 eV),高Tg (218-387 °C) 和高 εr (3.39-3.71 在200°C,1 kHz).
- 这些材料表现出极好的自我愈合能力,自我愈合能量为15.03mJ.
- 电容器在200°C时达到6.2 J cm−3和250°C时达到3.94 J cm−3的超级放电能量密度 (Uη90),具有高放电效率.
结论:
- 分子解策略有效地克服了介电材料特性固有的悖论.
- sAl-DG聚合物为下一代在极端条件下运行的高能量密度电容提供了有前途的解决方案.
- 在高电场和高温度下,堆叠的sAl-DG电容器的经过证明的运行可行性验证了它们的实际应用潜力.
更多相关视频
05:33Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
21.8K
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
4.6K
相关概念视频
Capacitor With A Dielectric
4.1K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.1K
Dielectric Polarization in a Capacitor
5.0K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
5.0K
MOS Capacitor
973
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
973
Spherical and Cylindrical Capacitor
6.0K
A spherical capacitor consists of two concentric conducting spherical shells of radii R1 (inner shell) and R2 (outer shell). The shells have equal and opposite charges of +Q and −Q, respectively. For an isolated conducting spherical capacitor, the radius of the outer shell can be considered to be infinite.
Conventionally, considering the symmetry, the electric field between the concentric shells of a spherical capacitor is directed radially outward. The magnitude of the field,...
Conventionally, considering the symmetry, the electric field between the concentric shells of a spherical capacitor is directed radially outward. The magnitude of the field,...
6.0K
Capacitors
534
Capacitors play a crucial role in car radios, where they filter and store frequencies to ensure clear signal reception. Essentially serving as energy storage devices, capacitors store energy within their electric field and are composed of two parallel conducting plates separated by a dielectric.
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
When a voltage source is connected to a capacitor, positive and negative charges accumulate on the opposite plates. This accumulation generates a potential difference that equals the product of the...
534
Energy Stored in Capacitors
626
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
626
