基于轮线的图像模式识别技术用于光激发-发射矩阵图的解释:质量和量化
Xiulian Yin1, Yingjin Li1, Mingjie Wei2
1School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China.
概括
一种新的光谱检索方法,CLIPR,解释光EEM光谱用于环境监测. 这种技术在识别和量化污染物方面达到很高的准确性,证明了未来应用的稳定性和通用性.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 环境科学 环境科学
背景情况:
- 光谱检索对于光谱分析至关重要,但对于光激发发射矩阵 (EEM) 光谱学缺乏进展.
- 在环境监测中,EME光谱被广泛使用.
研究的目的:
- 开发一种先进的光谱检索方法来解释EEM光谱.
- 为了提高消除噪声,特征提取和EEM数据的图像检索的准确性和效率.
主要方法:
- 开发了基于轮线的图像模式识别 (CLIPR) 技术.
- 实现了一个三级检索机制 (Lib1,Lib2,Lib3).
- 使用模型污染物和MOF-74 (Zn) 与28x4 EEM地图图像以及留出一个漏洞的交叉验证来验证该方法.
主要成果:
- 对于验证集 (>50μM),CLIPR实现了>79.61%的类内相似性和98.81%的准确性.
- 最好的定量结果显示RMSE/True值为3.09%,PhNH2-S1.1.的R2为0.99.
- 在特定度值下的未知样本集 (第1批>35μM,第2批>50μM) 中,获得了100%的识别精度.
结论:
- 该CLIPR方法证明了稳定性和概括能力,用于解释EEM光谱信息.
- 开发的光谱检索方法对于EEM数据分析是可行的.
- 这项工作为在EEM光谱分析中大规模准备参考数据奠定了基础.
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