从具有F/P的CaSO4·2H2O泥中选择性地通过CaCl2去除可溶性F
Xu Li1, Shuyu Lin1, Yaoyao Zhu1
1Department of Chemical Engineering, Tsinghua University, Beijing, China.
概括
这项研究引入了一种使用化 (CaCl2) 来选择性地从石膏 (CaSO4·2H2O) 泥中去除化 (F) 的新方法,同时保留 (P). 最佳的F去除和P保留发生在酸性pH (0.9-4.0) 时.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- (F) 和 (P) 在诸如石膏 (CaSO4·2H2O) 等工业泥中的共同污染给环境带来了挑战.
- 选择性去除F,同时保持P对于有效的废水处理和资源回收至关重要.
研究的目的:
- 开发和评估一种用于从含有F/P的CaSO4·2H2O泥中选择性去除化物的新方法.
- 为了确定最大限度地提高化物去除效率和最大限度地减少损失的最佳条件.
主要方法:
- 使用化 (CaCl2) 作为化物去除的沉剂.
- 在不同的pH值 (0.9-11.8),温度 (25°C) 和Ca/F比率 (2.5) 进行了实验.
- 采用热力学平衡计算来分析组件分布和降水行为.
主要成果:
- 在酸性pH (0.9-4.0) 和25°C下,可以达到最佳的F去除 (高达95.15%) 和P保留 (最小损失).
- 在pH值≥6.0时,的损失超过60%.
- 热力学分析显示,二进制和三进制的化和酸在更高的pH值 (≥4.4) 的共同沉阻碍了选择性的F去除.
结论:
- 开发的CaCl2沉方法在酸性条件下有效地从石膏泥中选择性去除化物.
- 保持酸性pH值范围 (0.9-4.0) 是成功去除化物的关键,同时保留.
- 了解降水机制是优化复杂工业废水中选择性污染物清除的关键.
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