含有硫的聚碳酸共聚合物:超薄的阻燃性,透明性和高的冲击性
Zongsheng Liu1, Meng Ma1,2, Kaiming Du1
1College of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|July 31, 2025
概括
合成了一种新的阻燃聚碳酸 (PC-SDPn),解决了先进电子产品的阻燃性,透明度和强度方面的挑战. 这种材料提供了卓越的消防安全,而不会损害光学和机械性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 阻燃性是指阻燃性是指阻燃性.
背景情况:
- 双甲聚碳酸 (PC) 努力平衡阻燃性与光学透明度和机械强度,特别是在电子和5G领域的超薄应用中.
- 现有的基于添加剂的修改往往会损害材料的基本特性.
研究的目的:
- 通过在聚合物骨干中化学嵌入硫基来开发一种新型的阻燃聚碳酸盐 (PC-SDPn).
- 为了克服PC中基于添加剂的阻燃剂固有的局限性.
主要方法:
- 4,4'-硫乙 (SDP) 和双A的界面聚凝合成PC-SDPn.
- 通过UL-94 V-0等级,限制氧指数 (LOI),峰值热释放率 (HRR) 和烟雾产生率 (SPR) 评估阻燃性.
- 评估光学透明度和机械强度 (有的冲击强度).
主要成果:
- PC-SDPn表现出极好的阻燃性,在0.8毫米厚度时达到UL-94 V-0.
- LOI增加到32.1%,而峰值HRR和SPR分别下降了55.7%和62.5%.
- PC-SDP5保持了高光透射率 (89.6%) 和口冲击强度 (88.3 kJ m-2),表现优于商用PC.
结论:
- 在PC骨干中化学嵌入硫基,通过激光火,气体稀释和炭火催化,提供有效的阻燃性.
- 开发的PC-SDPn为需要超薄,透明和阻燃材料的应用提供了有前途的解决方案.
- 潜在的应用包括微电子和防火透明建筑材料.
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