生物质和煤炭的氧气分离的化学循环:使用基于铜的氧气载体扩展到50kWth
A Abad1, A Filsouf1, I Adánez-Rubio1
1Department of Energy and Environment, Instituto de Carboquímica (ICB), CSIC, 50018 Zaragoza, Spain.
概括
化学循环与氧气解 (CLOU) 已升级到TRL 5,使用铜基载体捕获CO2. 这项技术通过生物质实现了93%的二氧化碳捕获效率,并证明了煤炭燃烧的有效性.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 燃烧科学 燃烧科学
- 碳捕获技术 碳捕获技术
背景情况:
- 有氧解的化学循环 (CLOU) 是一种新兴的二氧化碳捕获技术.
- 目前的发展已经达到技术准备水平4 (TRL4).
- 氧气载体为燃烧提供气态氧气,使二氧化碳能够有效分离.
研究的目的:
- 将CLOU技术的可行性提升到TRL 5.
- 为了研究磁性铜基氧载体 (Cu30MnFe) 的性能.
- 在使用生物质和煤炭燃料的连续单元中评估CLOU效率.
主要方法:
- 使用一个连续的CLOU单元与两个相互连接的循环流化床 (燃料和空气反应堆).
- 采用一个磁性铜基氧载体 (Cu30MnFe).
- 使用松木粉,其他两种生物质类型和塔尔丁斯基煤进行实验.
主要成果:
- 在886°C以松木粉实现93%的CO2捕获效率,总氧气需求为4.6%.
- 证明了碳剥离器在提高二氧化碳捕获效率时的有效性.
- 在高煤负载下,即使在900°C以下,也实现了低总氧气需求.
结论:
- 该研究成功地将CLOU技术推进到TRL 5,证明了其可行性.
- Cu30MnFe氧气载体在生物质和煤炭方面表现出有效的性能.
- 优化的操作参数可以带来高的二氧化碳捕获效率和低的氧气需求.
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