铁多复合物的非破坏性分析,用于重建铁油墨的历史配方
Salvatore Caterino1, Iulia-Maria Caniola1, Katja Sterflinger1
1Institute of Natural Sciences and Technology in the Arts, Academy of Fine Arts of Vienna, Vienna, Austria.
概括
这项研究揭示了不同色素如何影响铁油墨 (IGI) 组成. 分析光谱标记可以了解历史上的墨水配方和在"黑色时刻"等手稿中使用的材料.
科学领域:
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
- 艺术保护科学 艺术保护科学
背景情况:
- 由于不同的历史配方,铁油墨 (IGI) 呈现出显著的变化.
- 之前的研究集中在pH和铁度对IGI结构和检测的影响上.
- 这项研究研究了各种色素与铁的相互作用所带来的变异性.
研究的目的:
- 系统地合成和分析铁聚烯复合物,使用多种色素.
- 在IGI中识别标志着特定阳和铁相互作用的光谱标记.
- 应用多分析方法进行历史墨水的非破坏性分析.
主要方法:
- 合成铁多复合物与商业和树胆汁提取物.
- 使用光谱法和红外光谱法对原材料进行表征.
- 通过拉曼,红外和电子磁共振 (EPR) 光谱仪分析复合物.
主要成果:
- 建立了铁多复合物的光谱性质的参考数据集.
- 确定了与不同类型的色素和铁度相关的特定光谱标记.
- 展示了IGI材料识别的非破坏性多分析方法.
结论:
- 阳和铁之间的相互作用是IGI变异性的关键因素.
- 光谱分析为历史铁油墨的组成提供了宝贵的见解.
- 开发的方法为艺术保存和历史文档分析提供了一个强大的工具,具有确定的优点和局限性.
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