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相关概念视频

Ion Exchange01:17

Ion Exchange

663
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
663
Ion-Exchange Chromatography01:09

Ion-Exchange Chromatography

779
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
779
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

15.0K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
15.0K
Factors Affecting Activity Coefficient01:17

Factors Affecting Activity Coefficient

982
The extended Debye-Hückel equation indicates that the activity coefficient of an ion in an aqueous solution at 25°C depends on three partially interdependent properties: the ionic strength of the solution, the charge of the ion, and the ion size. 
The activity coefficient value for an ion is close to one when the solution has almost zero ionic strength, i.e., when the solution shows close to ideal behavior. As the ionic strength of the solution increases from 0 to 0.1 mol/L, a...
982
Intermolecular Forces03:13

Intermolecular Forces

61.2K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
61.2K
Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

33.6K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
33.6K

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相关实验视频

Updated: Sep 13, 2025

Using a Cyclic Ion Mobility Spectrometer for Tandem Ion Mobility Experiments
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Using a Cyclic Ion Mobility Spectrometer for Tandem Ion Mobility Experiments

Published on: January 20, 2022

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在广泛的度范围内的水性离子流动性.

Tian Huang1, Setare Mostajabi Sarhangi2, Steve Granick1

  • 1University of Massachusetts, Department of Polymer Science and Engineering, Amherst, Massachusetts 01003, USA.

Physical review letters
|July 31, 2025
PubMed
概括

分子动力学模拟和NMR测量显示,离子扩散随着度的增加而减缓,这是由于记忆放松时间而不是近似值. 这一发现澄清了缩溶液中静电和透力的相互作用.

科学领域:

  • 物理化学 物理化学
  • 计算化学的计算化学
  • 生物物理学的生物物理.

背景情况:

  • 酸溶液与生化过程 (H2PO4-) 和电池技术 (Li+) 有关.
  • 了解缩溶液中的离子扩散对于各种应用至关重要.

研究的目的:

  • 将分子动力学模拟与脉冲场梯度NMR测量LiH2PO4溶液中的离子扩散进行比较.
  • 研究静电和透力之间的关系及其对离子传输的影响.
  • 解释离子的度依赖的转化扩散.

主要方法:

  • 对LiH2PO4溶液的明确水分子动力学模拟.
  • 脉冲场梯度核磁共振 (NMR) 对离子扩散的测量.
  • 对静电和透力及其放松时间的分析.

主要成果:

  • 观察到影响离子扩散的静电和透力之间的补偿效应.
  • 柯克伍德方程被发现与精确的解决方案保持一致,但与传统的近似方法违反.
  • 在较高离子度下,转化扩散速度较慢的原因是记忆放松时间的增加.

结论:

  • 这项研究解释了度依赖的离子扩散是记忆放松时间的动态效应.

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Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
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Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
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Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone

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  • 力量组件之间的动态相关性导致度独立的总力变异和放松时间.
  • 这些发现协调了对缩LiH2PO4溶液的模拟和实验数据.