粘度是其理想的低度值和热力学函数的产物
L Marchioni1, M A Di Muro1, M Hoyuelos1
1Universidad Nacional de Mar del Plata, Instituto de Investigaciones Físicas de Mar del Plata, Departamento de Física, Facultad de Ciencias Exactas y Naturales, (IFIMAR - CONICET), , Deán Funes 3350, 7600 Mar del Plata, Argentina.
Physical review. E
|August 1, 2025
概括
一个新的假设提出粘度 (η) 等于状态函数 (φ) 乘以低度粘度 (η0). 分子动力学模拟证实了φ独立于恒温定位,支持其在密集流体粘度中的作用.
科学领域:
- 物理 物理学 物理
- 物理化学 物理化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 密度流体中的粘度 (η) 作为度的函数的行为尚未得到充分理解.
- 像博尔茨曼和查普曼-恩斯科格这样的现有理论准确地预测低度 (η0) 的粘度.
研究的目的:
- 提出并验证 η = φη0 的假设,其中 φ 是一个状态函数,可以解释高度的相互作用.
- 调查 φ 作为热力学状态函数的性质.
主要方法:
- 用分子动力学模拟来研究通过伪硬球或列纳德-斯潜力相互作用的粒子系统.
- 这些系统与Langevin恒温器相连,以引入缓冲 (t<0xE1><0xB5><0xA2>) 和噪声.
- 分析了不同噪声强度对粘度和拟议状态函数的影响.
主要成果:
- 模拟表明,虽然噪声强度影响 η 和 η0,但状态函数 φ 保持不变.
- 这种φ的不变性支持它仅仅是热力学状态的函数的假设.
结论:
- 提出的假设 η = φη0 为理解密度流体中的粘度提供了一个框架.
- 状态函数 φ 是独立于恒温参数的,证实了它的热力学性质.
- 这种方法为复杂流体系统中的传输系数提供了新的视角.
相关概念视频
Surface Tension, Capillary Action, and Viscosity
29.4K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
29.4K
Viscosity of Fluid
695
Viscosity measures the resistance a fluid offers to flow and deformation. It results from internal friction between layers of fluid moving relative to one another. Dynamic viscosity, denoted by the Greek letter mu (μ), quantifies the force needed to move one fluid layer over another. For Newtonian fluids like water and air, the relationship between the shearing stress and the rate of shearing strain is linear, meaning their viscosity remains constant regardless of the applied stress.
695
Viscosity
6.1K
When water is poured into a glass, it falls freely and quickly, whereas if honey or maple syrup is poured over a pancake, it flows slowly and sticks to the surface of the container. This difference in the flow of different kinds of liquids arises due to the fluid friction between the liquid layers and the liquid and the surrounding material. This property of fluids is called fluid viscosity. In this example, water has a lower viscosity than honey and maple syrup.
The SI unit of viscosity is...
The SI unit of viscosity is...
6.1K
pV-Diagrams
4.4K
The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
4.4K
Stokes' Law
1.6K
Viscous forces, like friction, are intermolecular forces that resist the relative motion of molecules over each other. When a solid body moves through a liquid, viscous forces drag it in the opposite direction. The force's magnitude depends on the solid's shape and size, as well as its speed and the liquid's coefficient of viscosity, density and temperature.
The expression for the force on a solid spherical object in a fluid is called Stokes' law. Stokes' law is valid only...
The expression for the force on a solid spherical object in a fluid is called Stokes' law. Stokes' law is valid only...
1.6K
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
35.4K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws.
35.4K


