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Updated: Sep 13, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
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Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

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在无重原子的烯衍生物中探索激素形成和超快速的系统间交叉

Luca M Sihn1, Robert B Vadell2, Rafael B Araujo3

  • 1Institute of Chemistry, University of São Paulo, 05508-000 São Paulo, Brazil. luca.sihn@usp.br.

Physical chemistry chemical physics : PCCP
|August 1, 2025
PubMed
概括

脱碳烯酸 (DRAc) 通过三重状态有效地形成基离子. 溶剂相互作用,特别是在水中,显著增强了这一过程,使得DRAc成为无重原子光化学的模型.

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Radical Formation: Addition

Radicals can be formed by adding a radical to a spin-paired molecule. This is typically observed with unsaturated species, where the addition of a radical across the π bond leads to the production of a new radical by dissolving the π bond. For example, the addition of a Br radical to an alkene yields a carbon-centered radical.
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Radical Formation: Elimination00:51

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