在高压下,GeAs的相位过渡和平面内异构性
Junbo Wang1,2, Zilong Zhang1,2, Shiquan Feng1,2
1College of Electronics and Information, Zhengzhou University of Light Industry, Zhengzhou, Henan, P. R. China. yyyk2002@163.com.
Physical chemistry chemical physics : PCCP
|August 1, 2025
概括
在高压下,化 (GeAs) 从单质转变为立方,成为金属. 释放后,它形成一个可逆的四角形金属相,揭示了其结构稳定性和异构性.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 甲 (GeAs) 是一种以其化学稳定性和在平面上的异构性而闻名的二维材料.
- 压力是调整二维材料结构和电子特性的一个关键参数.
研究的目的:
- 为了研究高压对相位过渡和GeAs在平面内异构性质的影响.
- 了解不同压力条件下的GeAs的结构稳定性和光学异构性.
主要方法:
- 拉曼光谱法 拉曼光谱法 拉曼光谱法
- 红外光谱学 红外光谱学 红外光谱学
- 高压电阻测量测量 高压电阻测量
- 密度函数理论 (DFT) 的计算.
主要成果:
- 在大约18.4 GPa左右,GeAs经历了一个不可逆转的单临床到立方相转换,形成一个金属岩盐结构.
- 在解压时,立方GeAs转化为可逆的四角形金属相.
- 角度分辨率偏振拉曼光谱显示单临GeAs中压力诱导的偏振方向偏移,而四边形GeAs保持稳定的异构性.
结论:
- 高压会导致地球气体的显著结构和电子变化,包括可逆相位过渡.
- 四角形GeAs在压力下表现出稳定的平面内光学异构性,与单临床阶段不同.
- 这些发现增强了对GeAs结构稳定性和异构性行为的理解,这对其潜在应用至关重要.
更多相关视频
09:45Epitaxial Growth of Perovskite Strontium Titanate on Germanium via Atomic Layer Deposition
Published on: July 26, 2016
12.5K
06:57Theoretical Calculation and Experimental Verification for Dislocation Reduction in Germanium Epitaxial Layers with Semicylindrical Voids on Silicon
Published on: July 17, 2020
2.3K
相关概念视频
Shearing Strain
The shearing strain represents a cubic element's angular change when subjected to shearing stress. This type of stress can transform a cube into an oblique parallelepiped without influencing normal strains. The cubic element experiences a significant transformation when exposed solely to shearing stress. Its shape alters from a perfect cube into a rhomboid, clearly demonstrating the effect of shearing strain. The degree of this strain is considered positive if it reduces the angle between the...
Transformation of Plane Stress
Studying stress transformation is essential in understanding how stress components within a material, like a cube under plane stress, change with rotation. This change is analyzed by considering a prismatic element within the cube. As the element rotates, the stress components acting on it—both normal and shearing stresses—change in magnitude and orientation. This change is quantified using trigonometric functions of the rotation angle, relating the forces acting on the rotated element's faces...
Transformation of Plane Strain
When analyzing elongated structures like bars subjected to uniformly distributed loads, it is essential to understand the transformation of plane strain when coordinate axes are rotated. This transformation helps to assess how material deformation characteristics vary with orientation, which is crucial in materials science and structural engineering.
Under plane strain conditions, typical for members where one dimension significantly exceeds the others, deformations and resultant strains are...
Under plane strain conditions, typical for members where one dimension significantly exceeds the others, deformations and resultant strains are...
Elastic Strain Energy for Normal Stresses
Strain energy quantifies the energy stored within a material due to deformation under loading conditions, a fundamental concept in materials science and engineering. The strain energy can be modeled when a material is subjected to axial loading with uniformly distributed stress. In this scenario, the stress experienced by the material is the internal force divided by the cross-sectional area, and the strain induced is directly proportional to this stress through the modulus of elasticity.
If...
If...
Elastic Strain Energy for Shearing Stresses
As discussed in previous lessons, strain energy in a material is the energy stored when it is elastically deformed, a concept crucial in materials science and mechanical engineering. This energy results from the internal work done against the cohesive forces within the material. When a material undergoes shearing stress and corresponding shearing strain, the strain energy density, which is the energy stored per unit volume, is calculated. Within the elastic limit, where the stress is...
Phase Transitions
A phase transition is the process in which a substance changes from one state of matter to another, like from a solid to a liquid, liquid to gas, or vice versa, at a specific temperature and under given pressure conditions. This change is spontaneous and is affected by alterations in temperature and pressure. These parameters impact the strength of the forces between molecules (intermolecular forces) in the substance.During a phase transition, both the initial and final phases of the substance...
