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Updated: Sep 13, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

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克里吉中间体 (CH2OO) 与异构异环合物的温度和压力依赖动力学:理论研究

Amit Debnath1, Balla Rajakumar1

  • 1Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.

The journal of physical chemistry. A
|August 1, 2025
PubMed
概括

计算研究显示,Criegee中间体 (CH2OO) 和furaldehydes之间的反应很慢. 由于大气寿命长,这些反应不会显著影响大气中的甲水平.

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Benzaldehyde, like formaldehyde, lacks an α hydrogen and cannot enolize to form an enolate. Hence, the reaction of benzaldehyde with a ketone in the presence of an aqueous base forms a single crossed product. This reaction is referred to as Claisen–Schmidt condensation.
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