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Updated: Sep 12, 2025

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

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Published on: February 10, 2023

在金属有机中的旋转交叉

Zhen Shao¹, Yin-Shan Meng^1,2, Yuan-Yuan Zhu³

¹State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, No. 2 Linggong Road, Dalian, 116024, China. liutao@dlut.edu.cn.

Dalton transactions (Cambridge, England : 2003)

|August 4, 2025

概括

旋转交叉金属有机 (SCO-MOCs) 是一种新型的分子开关. 最近的进展集中在通过智能材料和量子技术的协调工程来优化SCO行为.

科学领域:

材料科学材料科学材料科学
超分子化学超分子化学
量子科学是一个量子科学.

背景情况:

旋转交叉 (SCO) 材料作为刺激响应分子开关,使数据存储和传感中的应用成为可能.
SCO材料表现出双稳定性,将磁性与温度,压力,光或电场等外部刺激相合.
旋转交叉金属有机 (SCO-MOCs) 将SCO特性与分子功能相结合,提供可调整的架构和主机-客户互动.

研究的目的:

在过去十年中,回顾最近基于Fe (II) /Fe (III) 的SCO-MOC的进展.
系统地概述优化这些系统中的SCO行为策略.
讨论SCO-MOC的潜在应用和未来研究方向.

主要方法:

协调微环境工程来调整SCO属性.
创建SCO-MOCs的超分子组装策略.
对SCO行为的连接体场调制和空间限制效应的分析.
在SCO-MOC中调查客人封装机制.

主要成果:

突出了在协调子中增强上合组织特征的关键战略.
证明连接体设计和结构限制对SCO性能的影响.
在SCO-MOC框架内确定成功的客人封装方法.
展示SCO-MOC在药物输送和传感方面的潜力.

结论:

上合组织公开会议是下一代智能材料的有希望的平台.
对连接体场调制和超分子组合的进一步研究将释放先进的功能.
在量子技术和先进的传感应用方面,SCO-MOC具有变革性的潜力.

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