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Updated: Sep 12, 2025

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
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Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst

Published on: June 8, 2016

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通过短暂的激进-激进相互作用进行光燃料非光异构化消耗性自我组装系统

Yulian Zhang1, Xin Liang1, Cuiqin Yang1

  • 1State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, China.

Angewandte Chemie (International ed. in English)
|August 5, 2025
PubMed
概括

这项研究引入了一种新的光燃料消耗性自我组装系统,使用光激发激进化,避免缓慢的光异构化. 该系统将材料重新配置为螺旋式纳米纤维,提供时间控制和信息加密的应用.

关键词:
消散式自组装自组装方式螺旋式组件 螺旋式组件类似生命的材料.具有光学反应的光学响应.旋转与旋转相互作用.

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Radicals, the highly reactive species, gain stability by undergoing three different reactions. The first reaction involves a radical-radical coupling, in which a radical combines with another radical, forming a spin‐paired molecule. The second reaction is between a radical and a spin‐paired molecule, generating a new radical and a new spin‐paired molecule. The third reaction is radical decomposition in a unimolecular reaction, forming a new radical and a spin‐paired...
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A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
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A bond can be broken either by heterolytic bond cleavage to form ions or homolytic bond cleavage to yield radicals. A fishhook arrow is used to represent the motion of a single electron in homolytic bond cleavage. There are two main sources from which radicals can be formed:
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